In contrast to bead polymerization, the dispersion is not. It makes the reader aware of the potential commercial use of these recent developments. In emulsion polymerization, the water-insoluble monomer is predispersed in an aqueous phase. This book serves as both a professional reference for experienced researchers and a valuable text for newcomers to the field. These polymerization methods lead to the generation of the well delaminated polymer nanocomposites with a wide range of polymer matrices. This book provides a single comprehensive source of information about one of the most important facets of polymer nanocomposites technology: synthesis in emulsion and suspension. In an emulsion polymerization, the soap, or surfactant, is dissolved in water until the critical micelle concentration (CMC) is reached. ![]() Until now, most of the published research has been scattered throughout the literature. There are a number of recent advances in these methods such as the use of reactive surfactants, modified initiators, advanced clay surface modifications, use of a variety of fillers, inverse polymerization, and miniemulsion polymerization methods which have further led the generation of advanced exfoliated nanocomposites. However, advanced techniques provide a number of advantages as compared to the melt blending and lead to more uniform composites with enhanced properties. A comprehensive overview of the fundamentals of emulsion polymerization and related processes is presented with the object of providing theoretical and practical understanding to researchers considering use of these methods for synthesis of polymer colloids across a wide range of applications. The majority of the synthesis are carried out by melt blending which frequently result in the full exfoliation of the filler. ![]() A large number of polymer matrices were tried and nanocomposites with varying degrees of successes were achieved with these polymer systems. Abstract A review of relevant microscopic processes, both chemical and physical, which occur during suspension, bulk and emulsion polymerization (both before and after pressure drop) is given. Polymer nanocomposites revolutionized research in the composites area by achieving the nanoscale dispersion of the inorganic filler (clay platelets) in the polymer matrices after suitable surface modifications of the filler phase.
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